SHINODA Satoshi

写真a

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Title

Professor

Laboratory location

Sugimoto Campus

Homepage URL

http://www.sci.osaka-cu.ac.jp/chem/func/FC-eng/Top.html

Mail Address

E-mail address

Degree 【 display / non-display

  • Osaka City University -  Doctor of Science

Research Areas 【 display / non-display

Lanthanide Complex Chemistry, Molecular Recognition Chemistr, Function Chemistry

Research subject summary 【 display / non-display

  • Development of functional molecules based on lanthanide coordination chemistry, molecular recognition chemistry, and supramolecular chemistry

Research Interests 【 display / non-display

lanthanoid, molecular recognition, supramolecule, luminescence, near-infrared

Research Career 【 display / non-display

  • development and application of self-assembling lanthanide complex

    (Individual) Project Year :

    2009
    -
    2014

    Keyword in research subject:  self-assembly

  • Dynamic conversion of metal complex chirality and its application

    (Individual) Project Year :

    2008
    -
    2014

    Keyword in research subject:  metal complex chirality

  • Synthesis of transitionl and lanthanide mixed metal complexes

    (Individual) Project Year :

    2005
    -
    2010

  • Studies on Alkali Metal and Rare Earth Metal Complexes

    (Individual) Project Year :

    1999
    -
    2003

    Keyword in research subject:  Alkali Metal, Rare Earth Metal, Complex

  • Development and Application of Anion Recognition Molecules

    (Individual) Project Year :

    1998
    -
    2000

    Keyword in research subject:  Anion Recognition, Host-Guest

Association Memberships 【 display / non-display

  • THE CHEMICAL SOCIETY OF JAPAN

  • The Japanese Photochemistry Association

Awards & Honors 【 display / non-display

  • HGCS Japan Award of Excellence 2006

    2006  

Current Career 【 display / non-display

  • Osaka City University   Graduate School of Science   Molecular Materials Science Course   Professor  

Career 【 display / non-display

  • 2003.04
    -
    2006.03

    Osaka City University  

  • 1998.10
    -
    2003.03

    Osaka City University  

  • 1996.04
    -
    1998.09

    Osaka City University  

Graduate School 【 display / non-display

  • 1995.04
    -
    1996.03

    Kyoto University  Graduate School, Division of Natural Science 

  • 1993.04
    -
    1995.03

    Kyoto University  Graduate School, Division of Natural Science 

Graduating School 【 display / non-display

  •  
    -
    1993.03

    Kyoto University   Faculty of Science  

 

Published Papers 【 display / non-display

  • Transferrin–Terbium Complexesas Luminescent pH Sensing Devices

    J. Nanosci. Nanotechnol.  9   655 - 657 2009

  • pH-Responsive Cotton Effects in the d-d Transition Band of Self-Assembling Copper(II) Complexes with a Cholesteryl-Armed Ligand

    Sagami Takuya, Umemoto Shota, Tahara Yuhei O., Miyata Makoto, Yonamine Yusuke, Ishikawa Daisuke, Mori Taizo, Ariga Katsuhiko, Miyake Hiroyuki, Shinoda Satoshi

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN  90 ( 6 ) 739 - 745 2017.06  [Refereed]

    DOI

  • Luminescence sensing of weakly-hydrated anions in aqueous solution by self-assembled europium(III) complexes

    Sagami Takuya, Tahara Yuhei O., Miyata Makoto, Miyake Hiroyuki, Shinoda Satoshi

    CHEMICAL COMMUNICATIONS  53 ( 28 ) 3967 - 3970 2017.04  [Refereed]

    DOI

  • Chirality sensing and size recognition of N-Boc-amino acids by cage-type dimeric lanthanide complexes: chirality detection of N-Boc-aspartate anions via luminescence colour change

    Ito Hiroshi, Shinoda Satoshi

    CHEMICAL COMMUNICATIONS  51 ( 18 ) 3808 - 3811 2015  [Refereed]

    DOI

  • Chirality Sensing and Size Discrimination of Anions by Macrotricyclic Cyclen-Disodium Complexes

    Ito Hiroshi, Shinoda Satoshi

    CHEMISTRYOPEN  3 ( 6 ) 238 - 241 2014.12  [Refereed]

    DOI

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Books etc 【 display / non-display

  • 無機化学演習 : 大学院入試問題を中心に

    中沢 浩, 西岡 孝訓, 篠田 哲史, 廣津 昌和, 三宅 弘之, 板崎 真澄 (Part: Single Work )

    東京化学同人  2012

    CiNii

  • Supramolecular Optical Sensing

    (Part: Single Work )

    2009

  • Molecular Recognition and Sensing via Rare Earth Complexes

    (Part: Joint Work )

    Handbook on the Physics and Chemistry of Rare Earth, Elsevier, Amsterdam  2005

  • Spectral Analysis of Organic Compounds for Biginners, Study with CD-ROM

    (Part: Joint Work )

    2004

  • Click Chemistry

    (Part: Joint Work )

    2004

Review Papers (Misc) 【 display / non-display

  • Luminescent lanthanide complexes as analytical tools in anion sensing, pH indication and protein recognition

    Analyst  136   431 - 435 2011

  • Molecular Recognition of Cytochrome c by Designed Receptors for Generation of in vivo and in vitro Functions

    Chem. Sci.  2   2301 - 2305 2011

  • Molecular Recognition with Designed Heterocycles and Their Lanthanide Complexes

    Heterocyclic Supramolecules I (Topics in Heterocyclic Chemistry, Vol. 17)    1 - 42 2008

  • Nanoscale Substrate Recognition by Porphyrin Dendrimers with Patched Structures

    J. Inclusion Phenom. Macrocycl. Chem.  59   1 - 9 2007

  • Molecular Recognition by Lanthanide Complexes in Aqueous Solutions

    58 ( 10 ) 9 - 13 2007

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Conference Activities & Talks 【 display / non-display

  • Lanthanide Complexes as Luminescent Sensors for Anions in Aqueous Solutions

    S. Shinoda  [Invited]

    5th International Symposium on Rare Earth Resorce Utilization  2018.09 

  • Dynamic Switching of Molecular Assembly: Mononuclear/Hexanuclear Interconversion of Zn(II) Complex

    H. Miyake, H. Nakada, S. Yamashita, S. Shinoda

    43rd International Conference on Coordination Chemistry   2018.07 

Grant-in-Aid for Scientific Research 【 display / non-display

  • Development of imaging materials utilizing near-infrared luminescence of lanthanide complex

    Project/Area Number : 22350065  Grant-in-Aid for Scientific Research(B) Representative

    Project Year :

    2010
    -
    2012
     

     View Summary

    Multinuclear complexes containing lanthanide ions and transition metal ions were synthesized, and anion recognition and sensitized near-infrared lanthanide luminescence were realized with these complexes by utilizing characteristic properties of both meta

  • Synthesis of Space-Controlled Lanthanide Complexes and Their Functionalization

    Project/Area Number : 20245014  Grant-in-Aid for Scientific Research(A) Partaker / Other

    Project Year :

    2008
    -
    2010
     

    Partaker : SHINODA Satoshi, MIYAKE Hiroyuki

     View Summary

    A series of lanthanide complexes have been developed, which had characteristic coordination spheres of 1 or 10 nm diameters. They offered selective luminescence and circular dichroism sensing of inorganic anions, amino acids, proton, and protein derivatives based on unique lanthanide coordination chemistry. The lanthanide complexes with octadentate cyclen ligands further exhibited enough high dynamism to mediate the chirality transfer processes.

  • Elucidation of Luminescence Properties of d-f Heteronucl ear Complexes based on Armed Cyclen Ligands

    Project/Area Number : 19350034  Grant-in-Aid for Scientific Research(B) Representative

    Project Year :

    2007
    -
    2008
     

  • Construction of Lanthanide Luminescence Sensing Systems using Near-infrared Spectral Region

    Project/Area Number : 17550064  Grant-in-Aid for Scientific Research(C) Representative

    Project Year :

    2005
    -
    2006
     

     View Summary

    To apply the near-infrared luminescent properties of lanthanide ions for luminescence sensing in the solution states, enhancements of luminescence quantum yields and suppression of the luminescence quenching processes by using proper ligand architecture are necessary. For this purpose, the investigator utilized stable and highly luminescent "armed cyclen"-lanthanide complexes for hybridization with higher transition metal complexes. He has succeeded to develop stepwise synthetic procedures to obtain lanthanide-transition metal dinuclear complexes. When Pt(II) or Re(V) complexes were employed, their dinuclear complexes with lanthanide ions could be isolated as crystals, and their solid and solution structures were determined by X-ray crystallography and NMR analysis. Unprecedented structures including linear Re-O-Ln bonds were found in the Re(V) complexes.
    As the results, the energy transfer from the transition metal complexes to the energetically lower-lying lanthanide ions efficiently took place, giving near-infrared luminescence from the lanthanide ions. The dinuclear complexes including Re(V) moieties, which gave intense near-infrared luminescence even in solution at room temperature, were found to be novel near-infrared luminescent complexes. It was demonstrated that effective visible to near-infrared light conversion was possible by using the charge-transfer absorption bands of these transition metal complexes. The main results of this research are (1) that various lanthanide-transition metal complexes have been synthesized, (2) that the two complexes could be fixed in a proximity where strong interaction between two complexes are possible, and (3) that efficient visible to near-infrared light conversion was achieved. Based on these findings, the present research will lead to the development of metal complexes with novel photo-magnetic functions by combiing lighter transition metal complexes and lanthanide complexes.

 

Other educational activity and Special note 【 display / non-display

  • Contribution to University-wide Cross-training program

    (2017)