MIYAKE Hiroyuki

写真a

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Title

Associate Professor

Laboratory location

Sugimoto Campus

Mail Address

E-mail address

Degree 【 display / non-display

  • Osaka City University -  Doctor of Science

Research Areas 【 display / non-display

Coordination Chemistry, Supramolecular Chemistry, Inorganic chemistry, Organic chemistry

Research subject summary 【 display / non-display

  • Helical chirality in natural supramolecular systems is well controlled by some external stimuli, and offers several biological events such as gene expression and cellular processes. For example, right-handed DNA changes its helical sense to left-handed one (Z-DNA), caused by salt enrichment, cytosine methylation, and complexation with spermine, spermidine and metal cations. Several artificial systems including polyacetylenes, polysilanes and oligopeptides were reported to offer helicity inversion by chiral or achiral stimuli. A variety of helicated metal complexes have been recently developed, in which geometry of the metal center can determine the supramolecular helical structure. Although these previous examples included the kinetically inert metal centers and rendered the inversion processes slow and incomplete, I recently demonstrated that the kinetically labile Co(II) complex allowed dynamic and efficient helicity inversion as required for supramolecular switching devices.

Research Interests 【 display / non-display

Coordination Chemistry, Supramolecular Chemistry, Molecular Chirality, Host-Guest Chemistry, Molecular Recognition

Research Career 【 display / non-display

  • Synthesis and function of chiral metal complex

    (Collaboration in Organization)

    Keyword in research subject:  Chirality, Complex, Helicity

  • Synthesis and Function of Chiral Rare Earth Metal Complexes

    (Collaboration in Organization)

    Keyword in research subject:  Rare Earth Complex, circular dichroism, Luminescence

  • Activation of Inactive Small Molecule on Transition Metals

    (Collaboration in Organization)

    Keyword in research subject:  Transition Metal, Activation, catalysis

Association Memberships 【 display / non-display

  • The Chemical Society of Japan

  • Japan Society of Coordination Chemistry

  • American Chemical Society

  • Association of Research for Host-Guest and Supramolecular Chemistry

  • Molecular Chirality Research Organization

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Committee Memberships 【 display / non-display

  • 2016
     
     

    Association of Research for Host-Guest and Supramolecular Chemistry   Organizing Committee of Host-Guest Symposium

  • 2016
     
     

    Molecular Chirality Research Organization   Organizing Committee of Molecular Chirality Asia 2016

  • 2015
     
     

    Molecular Chirality Research Organization   the 15th International Conference on Chiroptical Spectroscopy (CD2015), Executive committee

  • 2008
    -
    2013

    Japan Society of Coordination Chemistry   Gender Equality Committee

  • 2003
    -
    2005

    Division of Biofunctional Chemistry, The Chemical Society of Japan   Secretary of Young Association of Division of Biofunctional Chemistry

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Awards & Honors 【 display / non-display

  • Award for Promotion of Young Researchers from Japan Society of Coordination Chemistry

    2005  

  • Selected for Young Scholar Lectures in Annual Meeting of The Chemical Society of Japan

    2005  

  • Award for Promotion of Young Researchers from Japan Bioindustry Association

    2008  

Current Career 【 display / non-display

  • Osaka City University   Graduate School of Science   Molecular Materials Science Course   Associate Professor  

Career 【 display / non-display

  • 2007.04
    -
    Today

    Osaka City University   Department of Chemistry, Graduate School of Science   Associate Professor

  • 2005.10
    -
    2007.03

    Osaka City University   Department of Chemistry, Graduate School of Science   Associate Professor

  • 1998.04
    -
    2005.09

    Osaka City University   Department of Chemistry, Graduate School of Science   Lecturer

  • 1994.10
    -
    1998.03

    Osaka City University   Department of Chemistry, Faculty of Science   Assistant Professor

Graduate School 【 display / non-display

  • 1992.04
    -
    1994.09

    Osaka City University  Graduate School, Division of Natural Science  Department of Chemistry 

  • 1990.04
    -
    1992.03

    Osaka City University  Graduate School, Division of Natural Science  Department of Chemistry 

Graduating School 【 display / non-display

  • 1986.04
    -
    1990.03

    Osaka City University   Faculty of Science  

 

Published Papers 【 display / non-display

  • Dynamic Structure-Conversion Programming of Metal Complexes in Response to External Stimuli: Chiral Sensing and Achiral Sensing

    Hiroyuki Miyake

    72   38 - 47 2018  [Refereed]

  • pH-Responsive Cotton Effects in the d-d Transition Band of Self-Assembling Copper(II) Complexes with a Cholesteryl-Armed Ligand

    Sagami Takuya, Umemoto Shota, Tahara Yuhei O., Miyata Makoto, Yonamine Yusuke, Ishikawa Daisuke, Mori Taizo, Ariga Katsuhiko, Miyake Hiroyuki, Shinoda Satoshi

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN  90 ( 6 ) 739 - 745 2017.06  [Refereed]

    DOI

  • Luminescence sensing of weakly-hydrated anions in aqueous solution by self-assembled europium(III) complexes

    Sagami Takuya, Tahara Yuhei O., Miyata Makoto, Miyake Hiroyuki, Shinoda Satoshi

    CHEMICAL COMMUNICATIONS  53 ( 28 ) 3967 - 3970 2017.04  [Refereed]

    DOI

  • Redox-Triggered Helicity Inversion in Chiral Cobalt Complexes in Combination with H+ and NO3- Stimuli

    Gregolinski Janusz, Hikita Masahiro, Sakamoto Tatsuya, Sugimoto Hideki, Tsukube Hiroshi, Miyake Hiroyuki

    INORGANIC CHEMISTRY  55 ( 2 ) 633 - 643 2016.01  [Refereed]

    DOI

  • Supramolecular Chirality in Dynamic Coordination Chemistry

    Miyake Hiroyuki

    SYMMETRY-BASEL  6 ( 4 ) 880 - 895 2014.12  [Refereed]

    DOI

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Books etc 【 display / non-display

  • “CoN2O4 complex”, ”CuN3OX/CuN3S complex”, AgN3 complex”, LnN6O3 complex”, “NdN4O4 complex”

    Hiroyuki Miyake (Part: Contributor )

    2019

  • Supramolecular chemistry strategies for naked-eye detection and sensing

    Kamaljit Singh, Paramjit Kaur, Hiroyuki Miyake and Hiroshi Tsukube, (ed) Tatsuya Nabeshima (Part: Joint Work )

    Synergy in Supramolecular Chemistry / CRC Press  2014

  • Molecular Recognition and Sensing via Rare Earth Complexes

    Satoshi Shinoda, Hiroyuki Miyake and Hiroshi Tsukube, (eds.) K. A. Gschneidner, Jr., J.-C. Bünzli, and V. Pecharsky (Part: Joint Work )

    Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam  2005

Review Papers (Misc) 【 display / non-display

  • Materials-Based Receptors: Design Principle and Applications

    Kamaljit Singh, Divya Sareen, Paramjit Kaur, Hiroyuki Miyake, and Hiroshi Tsukube

    Chem. Eur. J.  19   6914 - 6936 2013  [Refereed]  [Invited]

  • Helicity Induction and Switching: New Approach Using Labile Transition Metal Complexes

    Hiroyuki Miyake

    Bull. Jpn. Soc. Coord. Chem.  46   11 - 14 2005

  • Helix Architecture and Helicity Switching via Dynamic Metal Coordination Chemistry

    Hiroyuki Miyake and Hiroshi Tsukube

    Supramolecular Chemistry  17   53 - 59 2005

  • Molecular programming by metal complexes: construction and inversion switching of helical structure

    59   70 - 71 2004

  • Chirality Sensing by Lanthanide Complexes

    H. Miyake, S. Shinoda, H. Tsukube

    Kidorui  39   41 - 50 2001

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Conference Activities & Talks 【 display / non-display

  • Diastereoselective Induction of Left- or Right-Handedness in Octahedral Metal Complexes

    Hiroyuki Miyake  [Invited]

    Molecular Chirality Asia  (Harbin, China)  2018.06 

  • Stimuli-Responsive Helical Metal Complexes: Helicity Inversion, Expansion/Contraction, and Memorization

    Hiroyuki Miyake  [Invited]

    International Congress on Pure & Applied Chemistry (ICPAC) 2018  (Siem Reap, Cambodia)  2018.03 

  • Coordination Chemistry-Based Dynamic Structure Switching in Helical Metal Complexes

    Hiroyuki Miyake  [Invited]

    The 1st International Symposium on Coordination Ionic Compounds  (Osaka, Japan)  2017.12 

  • Dynamic Supramolecular Architecture via Asymmetric Coordination Chemistry

    Hiroyuki Miyake  [Invited]

    錯体化学会第66回討論会シンポジウム,”Inorganic Molecular/Supramolecular Systems for Future Development of Photofunctional Materials“  (福岡大学)  2016.09 

  • Dynamic Chiral Metal Complexes in Response to Combination of Multiple External Stimuli

    Hiroyuki Miyake  [Invited]

    Symmetry Festival  (Vienna, Austria)  2016.07 

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Charge of on-campus class subject 【 display / non-display

  • Senior Thesis Project

    (2018) University, Special course

  • General Experiments in Chemistry, S

    (2018) University, Teacher training course

  • Advanced Experiments in Chemistry, I

    (2018) University, Special course

  • Advanced Experiments in Chemistry, IV

    (2018) University, Special course

  • Practice of Inorganic Chemistry

    (2018) University, Special course

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Foreigner acceptance 【 display / non-display

  • Academic year : 2018

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    Number of foreigners accepted
    1

    France

  • Academic year : 2017

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    Number of International Students
    1
  • Academic year : 2015

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    Number of foreigners accepted
    1
  • Academic year : 2014

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    Number of foreigners accepted
    1
  • Academic year : 2013

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    Number of foreigners accepted
    2

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