SATOH Tetsuya

写真a

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Title

Professor

Laboratory location

Sugimoto Campus

Research Areas 【 display / non-display

Synthetic chemistry

Research Career 【 display / non-display

  • Development of Organic Synthesis Methods under Transition-Metal Catalysis

    (Individual) Project Year :

    1995.04
     
     

    Keyword in research subject:  C-H functionalization, organometallics, cross-coupling

Awards & Honors 【 display / non-display

  • The top 5% of reviewers for Angewandte Chemie

    2017  

  • Thomson Reuters Highly Cited Researchers 2016

    2016  

Current Career 【 display / non-display

  • Osaka City University   Graduate School of Science   Molecular Materials Science Course   Professor  

 

Published Papers 【 display / non-display

  • Synthesis of Benzo-Fused Cyclic Compounds via Rhodium-Catalyzed Decarboxylative Coupling of Aromatic Carboxylic Acids with Alkynes

    Inai Yasuhito, Usuki Yoshinosuke, Satoh Tetsuya

    SYNTHESIS-STUTTGART  53 ( 17 ) 3029 - 3036 2021.09  [Refereed]

    DOI

  • Synthesis of Indenones through Rhodium(III)-catalyzed [3+2] Annulation Utilizing a Recyclable Carbazolyl Leaving Group

    Ochiai Shiho, Sakai Asumi, Usuki Yoshinosuke, Kang Bubwoong, Shinada Tetsuro, Satoh Tetsuya

    公益社団法人 日本化学会 CHEMISTRY LETTERS  50 ( 4 ) 585 - 588 2021.04  [Refereed]

     View Summary

    <p>The rhodium(III)-catalyzed annulative coupling of 9-benzoylcarbazoles with internal alkynes proceeds efficiently through <i>ortho</i> C–H and C–N bond cleavages. This reaction provides direct access to variously substituted indanone derivatives. The carbazolyl leaving group can be readily recovered and reused for preparing the starting materials.</p>

    DOI CiNii

  • Synthesis of 7-Phenylindole Derivatives through Rhodium-Catalyzed Dehydrogenative Coupling of 2-(Acetylamino)-1,1'-biphenyls with Alkynes

    Michikita Ryudai, Usuki Yoshinosuke, Satoh Tetsuya

    ASIAN JOURNAL OF ORGANIC CHEMISTRY  10 ( 4 ) 868 - 871 2021.04  [Refereed]

    DOI

  • Synthesis of Substituted Indene Derivatives via Silver-Catalyzed Annulative 1:1 Coupling of Secondary Benzyl Alcohols with Alkynes

    H. Morisaka, K. Hirosawa, Y. Inai, Y. Usuki, T. Satoh

    Chemistry Letters  50   in press 2021.03  [Refereed]

  • A Theoretical Study of Product Selectivity in Rhodium- Catalyzed Oxidative Coupling Reaction Caused by the Solvation Effect

    M. Higashi, N. Shibata, S. Takeno, T. Satoh, M. Miura, H. Sato

    HETEROCYCLES  103   in press 2021.03  [Refereed]

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Books etc 【 display / non-display

  • Synthesis of Fused Heterocycles via Transition-Metal-Catalyzed C-H Functionalization

    Y. Usuki, T. Satoh (Part: Joint Work )

    Wiley-VCH  2022

  • Rhodium(III)-Catalyzed Annulative Carbon–Hydrogen Bond Functionalization

    T. Satoh, M. Miura (Part: Joint Work )

    Wiley-VCH  2019

  • Reactions Involving Elimination of CO2 and Ketones

    (Part: Joint Work )

    Cleavage of Carbon-Carbon Single Bonds by Transition Metals, Wiley-VCH  2016.04

  • Vinylation Using a Rhodium(III) Catalyst

    (Part: Joint Work )

    Georg Thieme•Science of Synthesis (Vol. Catalytic Transformations via C–H Activation 1)  2015.10

  • Metal-Catalyzed Single Bond Construction

    T. Satoh, M. Miura (Part: Joint Work )

    Wiley-VCH  2014

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Review Papers (Misc) 【 display / non-display

  • Copper-Mediated Intermolecular Direct Biaryl Coupling

    佐藤 哲也

    J. Am. Chem. Soc.  133巻, 7号, 2160-2162頁 2011  [Refereed]  [Invited]

    DOI

  • Copper-Catalyzed Annulative Amination of ortho-Alkynylphenols with Hydroxylamines: Synthesis of 3-Aminobenzofurans by Umpolung Amination Strategy

    佐藤 哲也

    Org. Lett.  13巻, 9号, 2395-2397頁 2011  [Refereed]  [Invited]

    DOI

  • Bond Activation and Molecular Activation

    SATOH Tetsuya

    Kagaku Dojin  2011  [Refereed]  [Invited]

  • Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C-H Bonds

    佐藤 哲也

    J. Org. Chem.  76巻, 1号, 13-24頁 2011  [Refereed]  [Invited]

    DOI

  • 不活性結合・不活性分子の活性化

    佐藤 哲也

    化学同人  2011  [Refereed]  [Invited]

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Conference Activities & Talks 【 display / non-display

  • Rhodium(III)- and Iridium(III)-Catalyzed Dehydrogenative Coupling of Aromatic Substrates with Unsaturated Compounds

    T. Satoh  [Invited]

    104th Canadian Chemistry Conference and Exhibition (IUPAC | CCCE 2021)  2021.08 

  • Regioselective C–H Functionalization under Rhodium(III)-Catalysis

    Tetsuya Satoh  [Invited]

    The 4th International Symposium on C-H Activation (ISCHA4)  2018.09 

  • Synthesis of pai-Conjugated Molecules via Transition-Metal-Catalyzed C-H Functionalization

    T. Satoh  [Invited]

    9th OCARINA International Symposium  2018.03 

  • Transition-Metal-Catalyzed Regioselective C-H Functionalization

    T. Satoh  [Invited]

    International Symposium on Pure & Applied Chemistry 2017  2017.06 

  • Transition-Metal-Catalyzed Transformation of Benzoic Acids and Related Compounds

    International Symposium on C–O Activation  2016.10 

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Grant-in-Aid for Scientific Research 【 display / non-display

  • Development of Catalytic Transformation Methods of Carboxylic Acids on Porous Reaction Field

    Project/Area Number : 18H04267  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area) Representative

    Project Year :

    2018.04
    -
    2020.03
     

  • Preparation of Organic Salt Crystals Containing Acene Structures and Their Application to Efficient Carrier Transport Materials

    Project/Area Number : 25288048  Grant-in-Aid for Scientific Research(B) Representative

    Project Year :

    2013.04
    -
    2016.03
     

    Partaker : TOHNAI NORIMITSU, HIRANO KOJI, HISAKI ICHIRO

     View Summary

    With a view to applying to the synthesis of building blocks for organic salt crystals, the regioselective direct functionalization methods of fused aromatic sulfonic acids and aromatic amines have been developed. Thus, rhodium-, iridium-, and ruthenium-catalyzed regioselective substitution at the approximate positions of sulfur-containing functional groups including sulfo and sulfonyl functions as well as an amino group has been achieved via directed C-H bond cleavage and alkene or alkyne insertion. A series of organic salt crystals have been prepared from thus obtained aromatic compounds and their supramolecular structures and basic properties have been investigated.

  • Development of New Methods for Construction of Organic Functional Materials Based on Selective Transformation of Ubiquitous Bonds

    Project/Area Number : 24225002  Grant-in-Aid for Scientific Research(S) Partaker / Other

    Project Year :

    2012.05
    -
    2017.03
     

    Partaker : SATOH Tetsuya, HIRANO Koji, NISHII Yuji

     View Summary

    In order to develop new, high performance catalysts for the direct transformation reactions of organic compounds through cleavage of C-H bonds as ubiquitous chemical bonds, various ligands have been examined for rhodium and palladium complexes. It has been found that using elaborated cyclopentadienyl and phosphorous ligands allows to improve their catalytic activity and to significantly expand the scope of applicable substrates. In addition, the utilization of cheap and abundant metals including copper and nickel as catalysts has also been examined, and a variety of unique transformations have been developed. Consequently, we have synthesized various pi-electron conjugated compounds with the developed catalyst systems and found a range of new interesting compounds that show semiconducting and solid state-luminescent properties.

  • Efficient Transformation of Alcohols in Fluorinated Ionic Liquids as Unique Reaction Media

    Project/Area Number : 24655080  Grant-in-Aid for challenging Exploratory Research Partaker / Other

    Project Year :

    2012.04
    -
    2014.03
     

    Partaker : SATOH Tetsuya, HIRANO Koji

     View Summary

    We succeeded in the synthesis of four novel imidazolium salts that bear polyfluoroaryl groups on the nitrogen atom of the imidazolium ring and preliminary investigated their physical properties. Additionally, we attempted to apply the above salts to some transition metal catalysis as a unique electron-deficient NHC ligand. On the other hand, to get a concise access to versatile molecules that contain the polyfluoroaryl groups, we developed a new synthetic method for preparation of (polyfluoroaryl)allenes by copper-catalyzed regioselective direct coupling of polyfluoroarenes with propargylic phosphates.

  • Development of Oxidative Cyclization Reactions via C-H CleavageBased on First Row Transition Metal Catalysts

    Project/Area Number : 22655027  Grant-in-Aid for challenging Exploratory Research Partaker / Other

    Project Year :

    2010
    -
    2012
     

    Partaker : SATOH Tetsuya, HIRANO Koji

     View Summary

    We have focused on the potential of first row transition metals, in particular, copper salts, and succeeded in the development of unique catalytic activity of copper/O2systems. Namely, the copper-catalyzed oxidative direct cyclization between N-methylanilines and electron-deficient olefins proceeded through C-H cleavage even under ambient conditions. In addition, when a similar copper/oxygen catalyst was applied to the reaction of heteroarenes with sulfoximines, the direct C-N bond formation occurred via both C-H and C-N cleavages.

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