SATOH Tetsuya

写真a

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Title

Professor

Laboratory location

Sugimoto Campus

Research Areas 【 display / non-display

Synthetic chemistry

Research Career 【 display / non-display

  • Development of Organic Synthesis Methods under Transition-Metal Catalysis

    (Individual) Project Year :

    1995.04
     
     

    Keyword in research subject:  C-H functionalization, organometallics, cross-coupling

Awards & Honors 【 display / non-display

  • The top 5% of reviewers for Angewandte Chemie

    2017  

  • Thomson Reuters Highly Cited Researchers 2016

    2016  

Current Career 【 display / non-display

  • Osaka City University   Graduate School of Science   Molecular Materials Science Course   Professor  

 

Published Papers 【 display / non-display

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Books etc 【 display / non-display

  • Reactions Involving Elimination of CO2 and Ketones

    (Part: Joint Work )

    Cleavage of Carbon-Carbon Single Bonds by Transition Metals, Wiley-VCH  2016.04

  • Vinylation Using a Rhodium(III) Catalyst

    (Part: Joint Work )

    Georg Thieme•Science of Synthesis (Vol. Catalytic Transformations via C–H Activation 1)  2015.10

  • Metal-Catalyzed Single Bond Construction

    T. Satoh, M. Miura (Part: Joint Work )

    Wiley-VCH  2014

  • Transition-Metal-Mediated Aromatic Ring Construction

    T. Satoh, M. Miura (Part: Joint Work )

    John Wiley and Sons  2013

Review Papers (Misc) 【 display / non-display

  • Copper-Mediated Intermolecular Direct Biaryl Coupling

    佐藤 哲也

    J. Am. Chem. Soc.  133巻, 7号, 2160-2162頁 2011  [Refereed]  [Invited]

    DOI

  • Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C-H Bonds

    佐藤 哲也

    J. Org. Chem.  76巻, 1号, 13-24頁 2011  [Refereed]  [Invited]

    DOI

  • Rhodium-Catalyzed Oxidative Coupling of Benzylamines with Alkynes through Dehydrogenation and Dehydrogenative Cyclization

    佐藤 哲也

    Chem. Lett.  40巻, 6号, 600-602頁 2011  [Refereed]  [Invited]

    DOI

  • Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

    佐藤 哲也

    J. Org. Chem.  76巻, 9号, 3024-3033頁 2011  [Refereed]  [Invited]

    DOI

  • Bond Activation and Molecular Activation

    SATOH Tetsuya

    Kagaku Dojin  2011  [Refereed]  [Invited]

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Conference Activities & Talks 【 display / non-display

  • Regioselective C–H Functionalization under Rhodium(III)-Catalysis

    Tetsuya Satoh  [Invited]

    The 4th International Symposium on C-H Activation (ISCHA4)  2018.09 

  • Synthesis of pai-Conjugated Molecules via Transition-Metal-Catalyzed C-H Functionalization

    T. Satoh  [Invited]

    9th OCARINA International Symposium  2018.03 

  • Transition-Metal-Catalyzed Regioselective C-H Functionalization

    T. Satoh  [Invited]

    International Symposium on Pure & Applied Chemistry 2017  2017.06 

  • Transition-Metal-Catalyzed Transformation of Benzoic Acids and Related Compounds

    International Symposium on C–O Activation  2016.10 

  • Rhodium(III)-Catalyzed Regioselective C–H Functionalization

    3rd International Conference on Organometallics and Catalysis  2016.08 

Grant-in-Aid for Scientific Research 【 display / non-display

  • Preparation of Organic Salt Crystals Containing Acene Structures and Their Application to Efficient Carrier Transport Materials

    Project/Area Number : 25288048  Grant-in-Aid for Scientific Research(B) Representative

    Project Year :

    2013.04
    -
    2016.03
     

    Partaker : TOHNAI NORIMITSU, HIRANO KOJI, HISAKI ICHIRO

     View Summary

    With a view to applying to the synthesis of building blocks for organic salt crystals, the regioselective direct functionalization methods of fused aromatic sulfonic acids and aromatic amines have been developed. Thus, rhodium-, iridium-, and ruthenium-catalyzed regioselective substitution at the approximate positions of sulfur-containing functional groups including sulfo and sulfonyl functions as well as an amino group has been achieved via directed C-H bond cleavage and alkene or alkyne insertion. A series of organic salt crystals have been prepared from thus obtained aromatic compounds and their supramolecular structures and basic properties have been investigated.

  • Efficient Transformation of Alcohols in Fluorinated Ionic Liquids as Unique Reaction Media

    Project/Area Number : 24655080  Grant-in-Aid for challenging Exploratory Research Partaker / Other

    Project Year :

    2012.04
    -
    2014.03
     

    Partaker : SATOH Tetsuya, HIRANO Koji

     View Summary

    We succeeded in the synthesis of four novel imidazolium salts that bear polyfluoroaryl groups on the nitrogen atom of the imidazolium ring and preliminary investigated their physical properties. Additionally, we attempted to apply the above salts to some transition metal catalysis as a unique electron-deficient NHC ligand. On the other hand, to get a concise access to versatile molecules that contain the polyfluoroaryl groups, we developed a new synthetic method for preparation of (polyfluoroaryl)allenes by copper-catalyzed regioselective direct coupling of polyfluoroarenes with propargylic phosphates.

  • Synthesis of Sulfur-Containing Fused Heteroaromatic Compounds via Oxidative Coupling

    Project/Area Number : 22550101  Grant-in-Aid for Scientific Research(C) Representative

    Project Year :

    2010
    -
    2012
     

     View Summary

    The oxidative coupling reactions of various aromatic substrates with alkynes and alkenes under transition-metal catalysis such as rhodium, palladium, and ruthenium were investigated. As a result, I succeeded in finding a number of new coupling reactions involving C-H bond cleavage. Furthermore, it was successfully shown that a wide range of sulfu- or other heteroatom-containing fused heteroaromatic compounds can be efficiently prepared by using these new reactions.

  • Development of Oxidative Cyclization Reactions via C-H CleavageBased on First Row Transition Metal Catalysts

    Project/Area Number : 22655027  Grant-in-Aid for challenging Exploratory Research Partaker / Other

    Project Year :

    2010
    -
    2012
     

    Partaker : SATOH Tetsuya, HIRANO Koji

     View Summary

    We have focused on the potential of first row transition metals, in particular, copper salts, and succeeded in the development of unique catalytic activity of copper/O2systems. Namely, the copper-catalyzed oxidative direct cyclization between N-methylanilines and electron-deficient olefins proceeded through C-H cleavage even under ambient conditions. In addition, when a similar copper/oxygen catalyst was applied to the reaction of heteroarenes with sulfoximines, the direct C-N bond formation occurred via both C-H and C-N cleavages.

  • Cross-Coupling through Selective Cleavage of C-H and C-C Bonds

    Project/Area Number : 20350050  Grant-in-Aid for Scientific Research(B) Partaker / Other

    Project Year :

    2008
    -
    2010
     

    Partaker : SATOH Tetsuya, HIRANO Koji

     View Summary

    The coupling reaction of suitably functionalized aromatic and heteroaromatic substrates with aryl halides, alkenes, and alkynes proceeded effectively in the presence of a palladium or rhodium catalyst. Especially, aromatic carboxylic acids was found to undergo multi-coupling via C-H and C-C bond cleavages to afford structurally interesting pi-conjugated compounds. Furthermore, a number of C-H transformation reactions of aromatic compounds by using copper and nickel catalysts have been developed.

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