NAKAJIMA Hiroshi

写真a

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Title

Professor

Laboratory location

Sugimoto Campus

Degree 【 display / non-display

  • The Graduate University for Advanced Studies -  Ph. D.

Research Areas 【 display / non-display

Bioinorganic Chemistry, Coordination Chemistry

Research Interests 【 display / non-display

Engneering of Natural protein, Thermophilic bacteria, Sensor Protein, Protein engineering, Protein from thermophilic Bacterium, Metal cluster, Metal Complex

Research Career 【 display / non-display

  • Development of novel bio-sensing mechanism using signal transducer protein

    (Individual) Project Year :

    2010.04
     
     

    Keyword in research subject:  Signal Transducer, Biosensor, Bioelectrochemistry

  • Exploration of chemical reactions driven by near infrared light

    (Individual) Project Year :

    2015.04
    -
    Today

    Keyword in research subject:  NIR responsive CO releasing molecule, Biocompatible Prussian Blue

  • Development of functional composites consisting of proteins and metal complexes

    (Individual) Project Year :

    2010.04
    -
    Today

    Keyword in research subject:  hollow proteins, proteins from thermophiles, electron transfer proteins, metal complexes

  • Development of functional materials exploiting proteins from thermophilic bacteria

    (Individual) Project Year :

    2003.04
     
     

    Keyword in research subject:  Thermophilus, Functional Material, Metalloprotein

Education summary 【 display / non-display

  • I'm in charge of lectures and lab experiments for undergraduates about inorganic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry. My lectures about group theory to understand the molecular symmetry of metal complexes and their reaction mechanism are given to graduate students.

Association Memberships 【 display / non-display

  • American Chemical Society

  • The Chemical Society of Japan

  • The Biophysiocal Society of Japan

  • The Electrochemical Society of Japan

Committee Memberships 【 display / non-display

  • 2017
    -
    2019

    15th International Symposium on Applied Bioinorganic Chemistry   Committee member

  • 2016
    -
    2018

    International Coordination Chemistry Conference 2018   Committee member

Current Career 【 display / non-display

  • Osaka City University   Graduate School of Science   Molecular Materials Science Course   Professor  

Career 【 display / non-display

  • 2015.04
     
     

    Osaka City University  

  • 2003
    -
    2015

    Nagoya University  

  • 2003
     
     

    Institute for Molecular Science  

  • 1996
    -
    2003

    Japan Advanced Institute for Science and Technology  

Graduate School 【 display / non-display

  •  
    -
    1996.03

    The Graduate University for Advanced Studies  Graduate School, Division of Mathematical and Physical Science  Department of Structural Molecular Science 

  • 1991.04
    -
    1993.03

    Osaka University  Graduate School, Division of Engineering  Division of Applied Chemistry 

Graduating School 【 display / non-display

  •  
    -
    1991.03

    Osaka University   Faculty of Engineering   Department of Applied Chemistry

 

Published Papers 【 display / non-display

  • Metal-metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt-Ag bonds

    Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

    Dalton Tansaction  49 ( 23 ) 7680 - 7683 2020  [Refereed]

    DOI

  • Reduction-triggered Ligand Dissociation of Trinuclear Complex Bearing Three Kinds of Metal-ligand Units

    Natsuki Yabune, Ryosuke Monju, Hiroshi Nakajima, Takanori Nishioka

    Bull Chem Soc Jpn  48   1511 - 1514 2019.12  [Refereed]

     View Summary

    A heterometallic trinuclear complex with three metal-metal bonds, which is constituted of three kinds of metal-ligand units bridged by two sulfido ligands, reacts with a 2-electron donor to afford an adduct accompanied with elongation of the metal-metal bonds. Cyclic voltammograms of the complexes showed that the adduct releases the 2-electron donor after electrochemical 1-electron reduction.A heterometallic trinuclear complex with three metal-metal bonds, which is constituted of three kinds of metal-ligand units bridged by two sulfido ligands, reacts with a 2-electron donor to afford an adduct accompanied with elongation of the metal-metal bonds. Cyclic voltammograms of the complexes showed that the adduct releases the 2-electron donor after electrochemical 1-electron reduction.

    DOI

  • CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands

    T. Nakae, M. Hirotsu, H. Nakajima

    Inorg. Chem.  57 ( 14 ) 8615 - 8626 2018.08  [Refereed]

  • The Arrangement of Two N-Heterocyclic Carbene Moieties in Palladium Pincer Complexes Affects Their Catalytic Activity towards Suzuki-Miyaura Cross-Coupling Reactions in Water

    Imanaka Yosuke, Shiomoto Naotoshi, Tamaki Mako, Maeda Yuri, Nakajima Hiroshi, Nishioka Takanori

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN  90 ( 1 ) 59 - 67 2017.01  [Refereed]

    DOI

  • Visible-light-induced release of CO by thiolate iron(III) carbonyl complexes bearing N,C,S-pincer ligands

    T. Nakae, M. Hirotsu, S. Aono, H. Nakajima

    Dalton Trans.  45 ( 41 ) 16153 - 16156 2016.11  [Refereed]

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Books etc 【 display / non-display

  • Creation of CO releasing complex sensitive to NIR light

    H. Nakajima (Part: Single Work )

    2019.04

  • Creation of CO releasing molecule triggered by NIR light irradiation

    H. Nakajima, M. Hirotsu (Part: Joint Work )

    2018.08

  • Protein and Enzyme Design, Vol 580, Methods in Enzymology

    NAKAJIMA, Hiroshi

    Academic Press, UK  2016

Conference Activities & Talks 【 display / non-display

  • フェリチンL134P変異体に内包されたプルシアンブルーの性質

    池上 裕太、西岡 孝訓、中島 洋

    日本化学会第101春季年会  2021.03 

  • Reactivity and stability of Prussian blue encapsulated in ferritin L134P mutant

    Y. Ikenoue, T. Nishioka, H. Nakajima,

    第70回錯体化学討論会  2020.09 

  • Roles of Sugar Substituents in Nickel Complexes Bearing a Chelating Bidentate N-Heterocyclic Carbene Ligand

    T. Nishioka, K. Minami, H. Nakajima

    3 The 25th International SPACC Symposium  2019.12 

  • Development of Trinuclear Complexes for Molecular Sensing

    N. Yabune, H. Nakajima, T. Nishioka

    2 The 25th International SPACC Symposium  2019.12 

  • Effect of axial ligand on NIR-responsive CO release from iron(III)-carbonyl complex

    H. Nakajima, T. Nakae, M. Hirotsu, T. Nishioka  [Invited]

    1. Post conference of 15th International Symposium on Applied Bioinorganic Chemistry   2019.06 

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Grant-in-Aid for Scientific Research 【 display / non-display

  • Creation of a protein-based nano-carrier that releases drug molecules depending on specific protease

    Grant-in-Aid for challenging Exploratory Research Representative

    Project Year :

    2014.04
    -
    2016.03
     

  • Signal transduction of a transcriptional activator by using dynamic interaction of electron transfer proteins

    Grant-in-Aid for Scientific Research on Innovative Areas Representative

    Project Year :

    2012.04
    -
    2014.03
     

Other external funds procured 【 display / non-display

  • Signal Transduction Mechanism Inspired by Natural Sensor Protein

    Project Year :

    2009.11
     
     

 

Other educational activity and Special note 【 display / non-display

  • Office hours

    (2020)

  • Improvement of educational methods

    (2020)

  • Contribution to FD activities

    (2020)

  • Contribution to FD activities

    (2020)

  • Contribution to FD activities

    (2020)

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